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美國(guó)布魯克海文儀器公司>技術(shù)文章>ZetaPALS Zeta電位測(cè)量應(yīng)用案例-17

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ZetaPALS Zeta電位測(cè)量應(yīng)用案例-17

閱讀:262          發(fā)布時(shí)間:2014-11-13
 文獻(xiàn)名: Enhancement of Oxygen Mass Transfer Using Functionalized Magnetic Nanoparticles
 
作者: Bernat Olle , Seyda Bucak , Tracy C. Holmes , Lev Bromberg , T. Alan Hatton , and Daniel I. C. Wang
Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139
 
摘要:Oxygen-transfer enhancement has been observed in the presence of colloidal dispersions of magnetite (Fe3O4) nanoparticles coated with oleic acid and a polymerizable surfactant. These fluids improve gas−liquid oxygen mass transfer up to 6-fold (600%) at nanoparticle volume fractions below 1% in an agitated, sparged reactor and show remarkable stability in high-ionic strength media over a wide pH range. Through a combination of experiments using physical and chemical methods to characterize mass transfer, it is shown that (i) both the mass transfer coefficient (kL) and the gas−liquid interfacial area (a) are enhanced in the presence of nanoparticles, the latter accounting for a large fraction of the total enhancement (80% or more), (ii) the enhancement in kL measured by physical and chemical methods is similar and ranges from 20 to 60% approximay, (iii) the enhancement in kL levels off at a nanoparticle volume fraction of approximay 1% v/v, and (iv) the enhancement in kLa shows a strong temperature dependence. These results are relevant to a wide range of processes limited by the mass transfer of a solute between a gas phase and a liquid phase, such as fermentation, waste treatment, and hydrogenation reactions.

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